International Journal For Multidisciplinary Research
A Widely Indexed Open Access Peer Reviewed Multidisciplinary Bi-monthly Scholarly International Journal
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Volume 6 Issue 1
A New Avenue in Hybrid Polyoxometalate Chemistry: Synthesis and Characterization of Mn (II) Functionalized POM Based Ionic Liquids
|Rajarshi Chatterjee, Sudeshna Dutta, Arabinda Mandal
|The synthesis of novel hybrid materials, combining the properties of organic and inorganic components in one compound, results in materials with unique physical and chemical properties. The organic-functionalization of POMs with covalently or non-covalently linked organic species opens a large spectrum of possibilities and research challenges. The development of such novel systems for metal−organic architectures is an attractive research field. Lacunary polyoxometalates (POMs) offer structurally well-defined coordination sites with various coordination directions; thus, lacunary POMs are ideal building blocks for inorganic−organic architectures. Here, we report the successful self-assembly of transition metal substituted anionic POM along with a new generation POM based ionic liquid. We know that the counter-cations in polyoxometalate chemistry play immense role beyond charge balance. That is why the resultant structure is furthermore utilized as a stable and reactive building block to synthesize POM based ionic liquid (POM-IL), an inorganic−organic architecture comprising 3d-metal substituted mono-lacunary POM and tetrabutyl ammonium (TBA) ligands.
|Organic-inorganic hybrid, Polyoxometalate based ionic liquid (POM-IL)
|Volume 6, Issue 1, January-February 2024
|A New Avenue in Hybrid Polyoxometalate Chemistry: Synthesis and Characterization of Mn (II) Functionalized POM Based Ionic Liquids - Rajarshi Chatterjee, Sudeshna Dutta, Arabinda Mandal - IJFMR Volume 6, Issue 1, January-February 2024. DOI 10.36948/ijfmr.2024.v06i01.11620
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