International Journal For Multidisciplinary Research

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A Widely Indexed Open Access Peer Reviewed Multidisciplinary Bi-monthly Scholarly International Journal

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Green synthesis of PdNP’s and its application towards Chemoselective Catalytic Transfer Hydrogenation of nitroarenes

Author(s) Mr. Nagesh D Pawar, Hari R. Pawar
Country India
Abstract A simple and greener approach towards the synthesis of PdNP's is developed using leaf extract Bryophylum pinnatum (BPLE). The XRD and HRTEM analyses of self assembled Pd@Brp suggest average size 20-30 nm. The Fourier transform infrared spectroscopy FTIR suggest the role of amide and poly-hydroxyl functionalities present in extract which acts as excellent reducing, encapsulating and stabilization of Pd@Brp. The beneficial catalytic activity Pd@Brp is explored for Chemo-selective Catalytic Transfer Hydrogenation (CCTH) of aromatic nitro compounds. The reductions were successfully carried out with other reducible functional groups achieving excellent yields. The catalytic activity of reusable Pd@Brp is sustained up to four successive cycles and therefore may be regarded as green protocol towards the synthesis of aromatic amines.
Keywords Palladium nanoparticles, CCTH Chemoselctive Catalytic Transfer Hydrogenation, BPLE Bryophylum Pinnatum Leaves Extract
Field Chemistry
Published In Volume 7, Issue 6, November-December 2025
Published On 2025-12-17
DOI https://doi.org/10.36948/ijfmr.2025.v07i06.63631

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